PTFE & PEEK Valve Seats Material Selection

The valve seat in an internal combustion gasoline or diesel engine is the surface against which an intake or an exhaust valve rests during the portion of the engine operating cycle when that valve is closed. The valve seat is a critical component of an engine in that if it is improperly positioned, oriented, or formed during manufacture, valve leakage will occur which will adversely affect the engine compression ratio and therefore the engine efficiency, performance (power and torque), exhaust emissions, and engine life.

Valve Seats

Valve seats are often formed by first press-fitting an approximately cylindrical piece of a hardened metal alloy, such as Stellite, into a cast depression in a cylinder head above each eventual valve stem position, and then machining a conical-section surface into the valve seat that will mate with a corresponding conical-section of the corresponding valve. Generally two conical-section surfaces, one with a wider cone angle and one with a narrower cone-angle, are machined above and below the actual mating surface, to form the mating surface to the proper width (called “narrowing” the seat), and to enable it to be properly located with respect to the (wider) mating surface of the valve, so as to provide good sealing and heat transfer, when the valve is closed, and to provide good gas-flow characteristics through the valve, when it is opened.

Inexpensive engines may have valve seats that are simply cut into the material of the cylinder head or engine block (depending on the design of the engine). Some newer engines have seats that are sprayed on rather than being pressed into the head, allowing them to be thinner, creating more efficient transfer of heat through the valve seats, and enabling the valve stems to function at a lower temperature, thus allowing the valve stems (and other parts of the valvetrain) to be thinner and lighter.

There are several ways in which a valve seat may be improperly positioned or machined. These include incomplete seating during the press fitting-step, distortion of the nominally circular valve seat surfaces such they deviate unacceptably from perfect roundness or waviness, tilt of the machined surfaces relative to the valve guide hole axis, deviation of the valve seat surfaces from concentricity with the valve guide holes, and deviation of the machined conical section of the valve seat from the cone angle that is required to match the valve surface. Automated quality control of inserted and machined valve seats has traditionally been very difficult to achieve until the advent of digital holography which has enabled high-definition metrology for measuring all of these listed deviations.

Material Name Main Properties Notes Temperature Range
VIRGIN PTFE Very low coefficient of friction and excellent chemical resistance. FDA approved -40°C to 260°C
15% Glass Filled PTFE Decreased compressive strength and lower deformation under load than virgin PTFE. Abrasive material -40°C to 260°C
25% Glass Filled PTFE Similar to 15% Glass better wear resistance, higher compressive strength and lower deformation under load. Abrasive material -40°C to 260°C
Stainless Steel Filled PTFE Extremely hard wearing. Excellent strength and stability under extreme loads and elevated temperatures. Can be used on steam and thermal fluid applications -40°C to 260°C
TFM Much denser polymer structure than Virgin PTFE. Displays better stress recovery. Modified TFE Polymer -40°C to 260°C
Carbon Graphite filled TFM Lower thermal expansion-contraction rate than conventional TFM. Ideal for use on steam and thermal fluid applications -40°C to 260°C and even 320°C on Thermal Fluid applications
UHMWPE Highly resistant to corrosive chemicals, with the exception of oxidising acids and organic solvents. Also known as High Modulus Polyethylene (HMPE) or High Performance Polyethylene (HPPE) -40°C to +80°C
PCTFE Excellent for cryogenic and Oxygen use. A homo-polymer of Chlorotrifluoroethylene -270°C to 260°C
Virgin PEEK 450G Excellent chemical resistance and mechanical properties at elevated temperatures. An organic polymer thermoplastic -40°C to 260°C
Carbon Filled PEEK Many similar properties to Virgin PEEK. Particularly suitable for elevated temperatures and high load situations. Low coefficient of friction and suitable for many extremely corrosive applications -40°C to 260°C
PEEK HT Retains all key features and benefits of PEEK 450G but retains physical properties to a higher temperature. Can be supplied in both virgin unfilled or as filled compounded material up to 260°C
Acetal and Delrin Displays good resistance to wear and deformation under load. Excellent for valve seat applications up to 80°C
VESPEL A polyimide material that has high temperature capabilities under load and is mainly used for heat transfer applications, hot gases and oils. Must not be used with STEAM  

Post time: Jan-24-2019